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            Prof. Dr. ISMAIL YILDIRIM

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February 2011

Ligand labilisation of [CrIII (N)6]3+ ((N) 2 = en, pn and tn), and [CrIII (N)4LCl]2+ (L = C6H5NH2, o-MeC6H4NH2 and p-...
Rajendran, A. and Anbalagan, K.

Molecular dynamics of the aquation reactions of the complexes [Cr(en)3]Cl3, [Cr(pn)3] Cl3,[Cr(tn)3] Cl3,[Cr(en)2 (C6H5NH2)Cl]Cl2,[Cr(en)2,(O-eC6H4NH2)Cl]Cl2 and [Cr(en)2(p-MeC6H4NH2)Cl]Cl2 have been extensively studied in mixed solvent media. Kinetics and thermodynamic parameters have been evaluated and the results are interpreted carefully in the light of statistical and regression models.

A facile green synthesis of 1-propylbenzoate promoted by ionic liquid under solvent less condition
Rajendran, A., Ramu, S. and Karthikeyan, C.

An esterification reaction was carried out to prepare 1-Propylbenzoate using silica sulphuric acid as an ionic liquid under solvent less condition. The catalytic activity and the amount of the target product 1-propylbenzoate were determined. The optimal reaction conditions were fixed and the product was characterized by FT-IR, 1H-NMR and 13C-NMR studies. The catalytic behavior of silica sulphuric acid was compared with that of sulphuric acid, a standard commercial catalyst. The ionic liquid...

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